Some springs are acid, as at Lyncestus and in Italy in the Velian country, at Teano in Campania, and in many other places. These when used in drinks have the power of breaking up stones in the bladder, which form in the human body.
"De architectura (Ten Books on Architecture)". Book by Marcus Vitruvius Pollio (Book VII, Chapter III, Section 17), circa 15 BC.